标题: Phenanthrene decomposition in soil washing effluents using UVB activation of hydrogen peroxide and peroxydisulfate

作者: Tao, YF (Tao, Yufang); Monfort, O (Monfort, Olivier); Brigante, M (Brigante, Marcello); Zhang, H (Zhang, Hui); Mailhot, G (Mailhot, Gilles)

来源出版物: CHEMOSPHERE  卷: 263  文献号: 127996  DOI: 10.1016/j.chemosphere.2020.127996  出版年: JAN 2021  

摘要: In this work, the decomposition of phenanthrene (PHE) in mimic and real soil washing (SW) effluents was investigated using UVB light assisted activation of hydrogen peroxide (H2O2) and peroxydisulfate (PDS) oxidation processes. The impact of oxidant concentration, initial pH, and coexisting inorganic anions (Cl-, HCO3- and NO3-) on PHE removal was evaluated. PHE degradation efficiency under UVB irradiation followed the order of UVB/PDS > UVB/H2O2 > UVB. The increase of PHE decomposition efficiency was observed with increasing oxidant dose in the range of 2-30 mM upon the two processes. It was found Cl- played different roles in the two activation systems depending on the solution pH and Cl- concentration. The influence of HCO3- on PHE elimination was negligible in the UVB/PDS process, while an inhibitory effect was observed in the UVB/H2O2 system. Nitrate inhibited the PHE decay in both UVB/H2O2 and UVB/PDS processes at the investigated pH 3.3, 7.1 and 8.6. Finally, the application of the two activation processes to the treatment of real SW effluents indicated that up to 85.0% of PHE degradation could be reached under 6 h UVB irradiation with PDS, indicating UVB/PDS process is a promising alternative for SW effluent treatment. (C) 2020 Elsevier Ltd. All rights reserved.

入藏号: WOS:000595802200133

PubMed ID: 33297035

语言: English

文献类型: Article

作者关键词: Soil washing effluent; Phenanthrene; Peroxydisulfate; Hydrogen peroxide; Photodegradation

地址: [Tao, Yufang; Zhang, Hui] Wuhan Univ, Dept Environm Sci & Engn, Wuhan 430079, Peoples R China.

[Tao, Yufang; Monfort, Olivier; Brigante, Marcello; Mailhot, Gilles] Univ Clermont Auvergne, Inst Chim Clermont Ferrand, SIGMA Clermont, CNRS, F-63000 Clermont Ferrand, France.

通讯作者地址: Zhang, H (通讯作者)，Wuhan Univ, Dept Environm Sci & Engn, Wuhan 430079, Peoples R China.

Mailhot, G (通讯作者)，Univ Clermont Auvergne, Inst Chim Clermont Ferrand, SIGMA Clermont, CNRS, F-63000 Clermont Ferrand, France.

电子邮件地址: eeng@whu.edu.cn; gilles.mailhot@uca.fr

影响因子：5.778