标题: Electrolyte engineering for efficient molten-carbonate electrolysis of CO2

作者: Yang, ZS (Yang, Zhengshan); Yin, HY (Yin, Huayi); Deng, BW (Deng, Bowen); Wang, DH (Wang, Dihua)

来源出版物: CHEMICAL ENGINEERING JOURNAL  卷: 473  文献号: 145146  DOI: 10.1016/j.cej.2023.145146  出版年: OCT 1 2023  

摘要: Molten carbonate electrolysis cells (MCEC) are a promising electrochemical CO2 capture and conversion process. However, the CO2 absorption and energy efficiencies are limited by the sluggish CO2 absorption kinetics and high electrode overpotentials. Herein, we propose an electrolyte engineering strategy to improve the CO2 absorption rate and reduce overpotentials at both the anode and the cathode. When BO33-was added into molten Li2CO3Na2CO3-K2CO3, the CO2 adsorption efficiency was improved from 3.3% to 60%, the overpotential was reduced by - 567 mV at the cathode and by - 238 mV at the anode under 200 mA cm-2. Accordingly, the energy efficiency reached 76.2 % at 650 & DEG;C. The improved CO2 absorption and energy efficiencies are thanks to the BO33that changes the thermodynamic properties of the molten carbonate, i.e., the BO33--CO32- complex reduces the energy barrier for the reduction of CO32- at the cathode and for the liberation of O2- that can be oxidized at a lower potential than CO32- at the anode. Therefore, the electrolyte engineering is an effective strategy for designing high-temperature CO2 electrolyzers with high CO2 absorption and energy efficiency.

作者关键词: Molten carbonate; CO 2 capture; CO 2 RR; Electrolyte engineering; Borate

KeyWords Plus: ELECTROREDUCTION; DIOXIDE; REDUCTION; NANOTUBES; CAPTURE; OPTIMIZATION; TEMPERATURE; CONVERSION; DESIGN; OXIDES

地址: [Yang, Zhengshan; Yin, Huayi; Deng, Bowen; Wang, Dihua] Wuhan Univ, Sch Resource & Environm Sci, Hubei Int Sci & Technol Cooperat Base Sustainable, Wuhan 430072, Peoples R China.

通讯作者地址: Yin, HY; Wang, DH (通讯作者)，Wuhan Univ, Sch Resource & Environm Sci, Hubei Int Sci & Technol Cooperat Base Sustainable, Wuhan 430072, Peoples R China.

电子邮件地址: yinhuayi@whu.edu.cn; wangdh@whu.edu.cn

影响因子：15.1