标题: Revealing the delithiation process of spent LiMn2O4 and LiNi 0.6 Co 0.2 Mn 0.2 O 2 batteries during the biomass-assisted gasthermal and carbothermal reduction

作者: Zhou, FY (Zhou, Fengyin); Ma, JY (Ma, Jianye); Wang, HY (Wang, Hongya); Cai, MY (Cai, Muya); Qu, X (Qu, Xin); Zhao, JJ (Zhao, Jingjing); Wang, DF (Wang, Danfeng); Cai, YQ (Cai, Yuqi); Wang, DH (Wang, Dihua); Yin, HY (Yin, Huayi)

来源出版物: JOURNAL OF HAZARDOUS MATERIALS  卷: 477  文献号: 135304  DOI: 10.1016/j.jhazmat.2024.135304  Published Date: 2024 SEP 15  

摘要: The utilization of biomass-assisted pyrolysis in the recycling of spent lithium-ion batteries has emerged as a promising and reliable process. This article furnishes theoretical underpinnings and analytical insights into this method, showcasing sawdust pyrolysis reduction as an efficient means to recycle spent LiMn2O4 2 O 4 and LiNi0.6- 0.6- Co 0.2 Mn 0.2 O 2 batteries. Through advanced thermogravimetry-gas chromatography-mass spectrometry analysis complemented by traditional thermodynamic demonstration, the synergistic effects of biomass pyrolysis reduction are elucidated, with minor autodecomposition and major carbothermal and gasthermal reduction pathways identified. The controlled manipulation of transition metals has demonstrated the capability to modulate surface pyrolysis gas catalytic reactions and facilitate the preparation of composite materials with diverse morphologies. Optimization of process conditions has culminated in recovery efficiency exceeding 99.0 % for LiMn2O4 2 O 4 and 99.5 % for LiNi0.6Co0.2Mn0.2O2. 0.6 Co 0.2 Mn 0.2 O 2 . Economic and environmental analyses underscore the

作者关键词: Spent lithium-ion battery; Biomass; Recycling; Carbothermal reduction; Gasthermal reduction

地址: [Zhou, Fengyin; Wang, Hongya; Cai, Muya; Qu, Xin; Zhao, Jingjing; Wang, Danfeng; Cai, Yuqi; Wang, Dihua; Yin, Huayi] Wuhan Univ, Sch Resource & Environm Sci, 299 Bayi Rd, Wuhan 430072, Peoples R China.

[Zhou, Fengyin; Wang, Hongya; Cai, Muya; Qu, Xin; Zhao, Jingjing; Wang, Danfeng; Cai, Yuqi; Wang, Dihua; Yin, Huayi] Wuhan Univ & Chilwee, Joint Ctr Green Mfg Energy Storage Mat, Wuhan 430072, Peoples R China.

[Wang, Dihua; Yin, Huayi] Hubei Int Sci & Technol Cooperat Base Sustainable, Wuhan 430072, Peoples R China.

[Wang, Dihua; Yin, Huayi] Hubei Prov Key Lab Biomass Resource Chem & Environ, Wuhan 430072, Peoples R China.

[Ma, Jianye] Zhekuang Heavy Ind Co Ltd, Heping Town Ind Pk, Huzhou 313100, Zhejiang Provin, Peoples R China.

通讯作者地址: Yin, HY (通讯作者)，Wuhan Univ, Sch Resource & Environm Sci, 299 Bayi Rd, Wuhan 430072, Peoples R China.

电子邮件地址: yinhuayi@whu.edu.cn

影响因子：12.2